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Iron(II) thiolates as reversible carbon monoxide carriers

✍ Scribed by Anikó Szakács-Schmidt; József Kreisz; Lászlo Markó; Zsuzsa Nagy-Magos; János Takács

Book ID
104138777
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
556 KB
Volume
198-200
Category
Article
ISSN
0020-1693

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✦ Synopsis

Solutions of several iron(I1) thiolato complexes in methanol, dimethylformamide or 2-ethoxyethanol reversibly absorb and release carbon monoxide at atmospheric pressure and 20-50 "C. Solutions of Fe(SPh),(H,NCH,CH,NHJ (CO), and of an anionic complex tentatively formulated as [Fe2(SPh),(CO),]-in 2-ethoxyethanol and of Fe(L-SCH,CH(NH~)COOEt),(CO), in dimethylformamide were found to be most effective for the separation of CO-N, gas mixtures.

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