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Reversal of π-facial diastereoselection in the hydride reduction of selenanones. Further application of the exterior frontier orbital extension model

✍ Scribed by Shuji Tomoda; Jian Zhang; Daisuke Kaneno; Masahito Segi *; Aojia Zhou

Book ID
104210381
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
219 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reversal of p-facial diastereoselection in the hydride reduction of 2-phenyl-4-selenanone (1b) and 6-phenyl-3-selenanone (2b) has been rationalized by the exterior frontier orbital extension model (EFOE model).

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