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Origin of π-facial stereoselectivity of nucleophilic addition to carbonyl compounds. Application of the exterior frontier orbital extension model to cyclohexanones with polar substituent

✍ Scribed by Shuji Tomoda; Takatoshi Senju


Book ID
108379294
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
623 KB
Volume
55
Category
Article
ISSN
0040-4020

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Origin of π-facial stereoselection in nu
✍ Shuji Tomoda; Takatoshi Senju 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 923 KB

The experimental dataof x-facial stereoselection of 5-substituted adamaman-2-ones, 5aza-adamantan-2-oncs, and nor-and homo-adamantanones have been successfully rationalized by the exterior frontier orbital extension model (EFOE model). The values of g-plane-divided accessible space (PDAS), which rep