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Reversal of the ee in enantioselective hydrogenation of activated ketones in continuous-flow fixed-bed reactor system

✍ Scribed by Szabolcs Cserényi; György Szőllősi; Kornél Szőri; Ferenc Fülöp; Mihály Bartók


Book ID
116343545
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
427 KB
Volume
12
Category
Article
ISSN
1566-7367

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New data in the enantioselective hydroge
✍ György Szöllősi; Szabolcs Cserényi; Katalin Balázsik; Ferenc Fülöp; Mihály Bartó 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 746 KB

The origin of rate enhancement in the enantioselective heterogeneous catalytic hydrogenation of ethyl pyruvate on Pt modified with the parent cinchonas, as compared to the unmodified Pt, was studied in a solvent mixture toluene/AcOH 9/1. Hydrogenation experiments were carried out in a continuousflow