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New data to the origin of rate enhancement on the Pt-cinchona catalyzed enantioselective hydrogenation of activated ketones using continuous-flow fixed-bed reactor system

✍ Scribed by György Szöllősi; Szabolcs Cserényi; Ferenc Fülöp; Mihály Bartók


Book ID
113686553
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
350 KB
Volume
260
Category
Article
ISSN
0021-9517

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New data in the enantioselective hydroge
✍ György Szöllősi; Szabolcs Cserényi; Katalin Balázsik; Ferenc Fülöp; Mihály Bartó 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 746 KB

The origin of rate enhancement in the enantioselective heterogeneous catalytic hydrogenation of ethyl pyruvate on Pt modified with the parent cinchonas, as compared to the unmodified Pt, was studied in a solvent mixture toluene/AcOH 9/1. Hydrogenation experiments were carried out in a continuousflow