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Reversal of enantioselectivity using tethered bisguanidine catalysts in the aza-Henry reaction

✍ Scribed by Helena M. Lovick; Forrest E. Michael


Book ID
108285349
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
183 KB
Volume
50
Category
Article
ISSN
0040-4039

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The First Enantioselective Aza-Diels-Alder Reactions of Imino Dienophiles on Use of a Chiral Zirconium Catalyst. -The first examples of catalytic, enantioselective DA reactions of imine dienophiles with Danishefsky's dienes are reported. The free hydroxyl group of the aldimines is crucial with resp