## Abstract A new method for recycling chiral bis(oxazoline)–copper complexes is described based on the formation of charge‐transfer complexes, their subsequent precipitation, and reuse after addition of new substrates. The conditions to perform this procedure were optimized in the presence of thre
Reusable montmorillonite-entrapped organocatalyst for asymmetric Diels–Alder reaction
✍ Scribed by Takato Mitsudome; Kenta Nose; Tomoo Mizugaki; Koichiro Jitsukawa; Kiyotomi Kaneda
- Book ID
- 104095585
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- French
- Weight
- 168 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
A chiral organocatalyst was successfully entrapped by montmorillonite clay using the cation-exchange method. The mont-entrapped organocatalyst acted as a highly efficient and reusable heterogeneous catalyst for the asymmetric Diels-Alder reaction, without loss of its initial activity.
📜 SIMILAR VOLUMES
A new class of C 2 -symmetric 3,3 0 -dialkoxy-2,2 0 -bipyrrolidines have been designed and developed for asymmetric organocatalytic Diels-Alder reactions of a,b-unsaturated aldehydes. The bipyrrolidines combined with HClO 4 were found to be effective organocatalysts for enantioselective Diels-Alder
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