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Retro-ene reactions in heterocyclic synthesis. IV. A new synthetic method for 6-hydroxypyrimidin-4(3H)-ones and 1,3,5-triazine-2,4(1H,3H)-diones

✍ Scribed by Kunio Ito; Shingo Miyajima

Publisher
Journal of Heterocyclic Chemistry
Year
1999
Tongue
English
Weight
210 KB
Volume
36
Category
Article
ISSN
0022-152X

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✦ Synopsis

(N) - (t)-Butylbenzamidines 1 reacted with diphenyl phenylmalonate or diphenyl methylmalonate to give 6-hydroxypyrimidin-4(3H)-ones 4 or 5 . Amidines 1 on reaction with diphenyl imidodicarboxylate afforded (1,3,5)-triazine- (2,4(1 H, 3 H))-diones 8 .

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