Free-radical polymerization of styrene was carried out in the presence of chain transfer agents (CTAs) with functionality, f ϭ 1-4. The size exclusion chromatography (SEC) with an ultraviolet absorption detector (UV) was used to measure the molecular weight distribution (MWD). A Monte Carlo simulati
Retardative chain transfer in free radical free-radical polymerisations of vinyl neo-decanoate in low molecular weight polyisoprene and toluene
✍ Scribed by M.J. Monteiro; N. Subramaniam; J.R. Taylor; B.T.T. Pham; M.P. Tonge; R.G. Gilbert
- Book ID
- 108366254
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 214 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0032-3861
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📜 SIMILAR VOLUMES
## Abstract In this part of the series, the influence of polyfunctional chain transfer agents with transfer constant __C__ ≤ 1 on the molecular weight distribution was studied. The analytical expressions for the number‐ and weight‐average degree of polymerization, and dispersion index were derived
## Abstract The theoretical approach to free‐radical polymerization in the presence of polyfunctional transfer agents can be derived in a simple way if the effects of primary chains and termination reactions are neglected. Under these conditions, and for values of the chain transfer constant __C__
## Abstract Polymerization of methyl methacrylate was carried out in the presence of polyfunctional chain transfer agents: 1,6‐hexanedithiol, trimethylolpropane^b^ tris(mercaptoglycolate) and pentaerythritol tetrakis(3‐mercaptopropionate). The theoretical results reported in the preceding papers ar