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Restricted rotation of the C6F5 ligand in cyclopentadienyl π-complexes of titanium (IV)

✍ Scribed by Jean Claude Leblanc; Claude Moïse

Book ID: 102530278
Publisher: John Wiley and Sons
Year: 1980
Tongue: English
Weight: 292 KB
Volume: 14
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270140302

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✦ Synopsis

Abstract

^1^H and ^19^F spectra of methoxypentafluorophenyltitanocene complexes have been analysed. They show the possibility of coupling between the methyl protons of the methoxy group and the two ortho fluorine atoms of the pentfluorophenyl ligand. Furthermore, anisochrony of the two ortho and the two meta fluorine atoms is detected in some cases. The analysis of conformational factors is presented.

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