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Restricted rotation of the amino group bonded to thiamin and to 2-(1-hydroxyethyl)thiamin and the question of intramolecular amino group catalysis

โœ Scribed by Zoltewicz, John A.; Baugh, Thomas D.; King, Roy W.


Book ID
126298362
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
469 KB
Volume
43
Category
Article
ISSN
0022-3263

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Barriers to rotation of the dimethylamin
โœ C. H. J. Wells ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 171 KB ๐Ÿ‘ 1 views

## Abstract The free energy of activation for rotation about the exocyclic C๏ฃฟN bond of the dimethylamino group of some 6โ€substituted 2โ€aminoโ€4โ€(__N__,__N__โ€dimethylamino)pyrmidines has been determined using ^1^H NMR line shape analysis. The results are discussed in terms of the relative electronโ€wi