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Response to comment by T. J. Wallington and E. W. Kaiser on The Fluorine Atom Initiated Oxidation of CF3CFH2 (HFC-134a) Studied by FTIR Spectroscopy by A. S. Hasson, et al.

✍ Scribed by A. S. Hasson; C. M. Moore; I. W. M. Smith

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 75 KB
Volume: 31
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1999)31:5<399::aid-kin11>3.0.co;2-t

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Comment: The fluorine atom initiated oxi

Comment: The fluorine atom initiated oxidation of CF3CFH2 (HFC-134a) studied by FTIR spectroscopy by A. S. Hasson, et al.

✍ T. J. Wallington; E. W. Kaiser 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 118 KB 👁 1 views

HFC-134a is an important chlorofluorocarbon replacement which degrades in the atmosphere to give CF 3 CFHO radicals. Hasson et al. [1] have studied the fluorine atom initiated oxidation of HFC-134a and reported values for the rate constant ratio k 1 /k 2 at 700 Torr total pressure and 298 -357 K. CF

The fluorine atom initiated oxidation of

The fluorine atom initiated oxidation of CF3CFH2 (HFC-134a) studied by FTIR spectroscopy

✍ Alam S. Hasson; Christopher M. Moore; Ian W. M. Smith 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 197 KB

Experiments have been carried out on the oxidation of CF 3 CFH 2 (HFC-134a). Reaction was initiated by continuous photolysis of F 2 in the near-ultraviolet. The F atoms produced abstracted a hydrogen atom from CF 3 CFH 2 initiating oxidation in gas mixtures containing O 2 and made up to a total pres