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Resonant degenerate four wave mixing detection of HCO

✍ Scribed by Gerard Hall; Arthur G. Suits; Benjamine J. Whitaker


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
577 KB
Volume
203
Category
Article
ISSN
0009-2614

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✦ Synopsis


The HCO radical has been detected by degenerate four wave mixing (D4WM) spectroscopy following 308 nm photolysis of CH,CHO. Spectra have been obtained for the (0, I 1,O) 6 (0, 0,O) and (0, 10,O) + (0, 0,O) vibronic transitions ofthe A%"&% *A band system, and the effects of Renner-Teller rovibronic coupling to the dissociative 2 state have been investigated. The most important observation is the enhanced spectral resolution that is obtained in D4WM spectroscopy, which results from the Lorentzian cubed line profile that is predicted for degenerate four wave mixing spectroscopy in the limit of extreme homogeneous broadening (stationary atom limit). We estimate the detection limit to be approximately I x 10" cm-s quantum state-'.


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