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Resonance raman study of the first absorption band of H2S

✍ Scribed by Richard J. Brudzynski; Roseanne J. Sension; Bruce Hudson

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 586 KB
Volume: 165
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)87027-o

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✦ Synopsis

Raman spectra of hydrogen sulfide excited at nine wavelengths throughout its first absorption feature in the 180-250 nm region are reported. The spectra are dominated by transitions to S-H stretching overtone states. Several bands corresponding to combinations involving one quantum of the bending vibration are also observed. The intensity pattern varies significantly with excitation energy. These results are interpreted in terms of the nature and number of the excited state potential energy surface(s) in this spectral region.

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