Raman spectra of hydrogen sulfide excited at nine wavelengths throughout its first absorption feature in the 180-250 nm region are reported. The spectra are dominated by transitions to S-H stretching overtone states. Several bands corresponding to combinations involving one quantum of the bending vi
Direct absorption spectroscopy of the first excited electronic band of jet-cooled H2S
โ Scribed by Kathleen O'Brien Lantz; Veronica Vaida
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 739 KB
- Volume
- 215
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The absorption spectrum of jet-cooled H&3 was measured in the energy region of 1700-2300 A. The anomalous intensity in the tail is shown not to be due to excitation from excited rotational levels of the ground state. The spectral information indicates two electronic states contribute to the first absorption band of HrS. Clustering within the jet is shown to be an effective tool for identifying Rydberg states versus valence states.
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