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Resonance Raman Study of Spin-Crossover [Fe(Htrz) 2 (trz)](BF 4 )·H 2 O Particles Coated with Gold

✍ Scribed by Tobon, Yeny A.; Etrillard, Céline; Nguyen, Olivier; Létard, Jean-François; Faramarzi, Vina; Dayen, Jean-François; Doudin, Bernard; Bassani, Dario M.; Guillaume, François

Book ID
118758170
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
857 KB
Volume
2012
Category
Article
ISSN
1434-1948

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## Abstract By changing the surfactant/water ratio, nanoparticles of the iron(II) spin crossover material, [Fe(NH~2~‐trz)~3~]Br~2~⋅3 H~2~O (with NH~2~‐trz=4‐amino‐1,2,4‐triazole), have been synthesised from 1 μm down to 30 nm (see figure). Magnetic and reflectivity experiments indicate that the cri