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Resonance Raman spectra of phenoxy and monosubstituted phenoxy radicals

✍ Scribed by Hitoshi Shindo; Jiro Hiraishi

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
451 KB
Volume
12
Category
Article
ISSN
0377-0486

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The Raman spectrum of the phenohy radical produced durmg the course of oxidation of phenol by the Ce(IV) Eon was measured by use of a stopped-flolr method and a multichannel detechon method Five Raman bands were observed in the frequency region belo\\ 1700 cm-' \_ The time dependence of the spectrum

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The mthor 11.1s reported [I I, with thr.usht, the K~m.m spectrum of .m mtermcdlatc obscrvcd during tlw course of the o\tdatlon of phenol by Ce"+.

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## Abstract In this work, the role of phenoxy radicals in polychlorinated dibenzo‐__p__‐dioxins and polychlorinated dibenzofurans (PCDD/F) formation was investigated by studying the slow oxidation of 2‐chlorophenol (2‐CP) and 2‐chloroanisole (2‐CA) at a gas‐phase concentration of 4 ppm (∼2.1 × 10^4