The mthor 11.1s reported [I I, with thr.usht, the K~m.m spectrum of .m mtermcdlatc obscrvcd during tlw course of the o\tdatlon of phenol by Ce"+.
Raman spectrum of the phenoxy radical
β Scribed by H. Shindo; J. Hiraishi
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 356 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The Raman spectrum of the phenohy radical produced durmg the course of oxidation of phenol by the Ce(IV) Eon was measured by use of a stopped-flolr method and a multichannel detechon method Five Raman bands were observed in the frequency region belo\ 1700 cm-' _ The time dependence of the spectrum \as also foilo\red.
π SIMILAR VOLUMES
Pulse ndrolysls studies show that phenokyl nchcd rcacis .11 diflusion controlled r&s. Conccntratlons on the tlmc scJc of stopped flow c\pcriments cannca be substantially above IO -s hl so that in the absence of resonance crhanci ~n:nt the Ramzi spectrum rcportcd by Shmdo and Hmush~ cannot be dsagncd