Transient Raman spectra of anisole cation (C6HJOCH$') and its para methyl derivative are reported. These radicals were prepared on the 100 ns time scale by electron transfer reactions in aqueous solution. The structural contents in these Raman spectra are much more extensive than in the recently stu
β¦ LIBER β¦
Resonance Raman spectra of metallooctaethylporphyrin cation radicals with alu and a2u orbital character
β Scribed by Kim, Dongho; Miller, Lisa A.; Rakhit, Gopa; Spiro, Thomas G.
- Book ID
- 120209360
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 687 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0022-3654
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Resonance Raman (RR) and absorption spectra and cyclic voltammograms were measured for 1,4-benzoquinone (BQ) and its anion radical in various solvents. The absorption maxima of around 440 and 320 nm (BQ-~) B QαΊ½xhibit a good linear correlation both with acceptor numbers (AN) of solvents and the stand