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Resonance raman scattering of the tetracyanoethylene-anisole electron donor/acceptor complex

✍ Scribed by P.Waage Jensen

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
317 KB
Volume
39
Category
Article
ISSN
0009-2614

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✦ Synopsis

The Raman spectrum of the tetracyanoethylene-anisole EDA complex was measured using seven lines of an Ar laser. The excitation profiles for the TCNEC=C 2nd =N stretching vibrations have distinct maxima at the absorption maximum cf the high wavelength fl band. The depolarization ratios rise from about l/3 at the absorption maximum to much higher values between the two CT bands. Similar results are found for some anisole lines although only about 1% qf the anisole mokuks are complexed.

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