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Preresonance Raman intensity studies in electron donor/acceptor complexes of tetracyanoethylene

✍ Scribed by K.H. Michaelian; K.E. Rieckhoff; E.M. Voigt

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
544 KB
Volume
30
Category
Article
ISSN
0009-2614

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Raman spectrum of the tetracyanoethylene-hexamethylbenzene EDA complex was recorded using seven lines of an Ar laser and one from a Kr laser. By comparison with spectra recorded of the donor and acceptor moIecuks separately, it was found that some of the lines of the complex were up to 393 times str

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WC present a simple theoretical model which qualitatively explains the previously reported unusual features of the fesonance Raman (RR) excitation profies of electron doaorlacceptor complexes of TCNJZ with aromatic donors, in particuiar the pronounced red-shift of the RR cxcitation protΓ―le vis 5 vis