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Resonance effect in solvolysis of 1-methylbenzyl chlorides

โœ Scribed by Mizue Fujio; Toshikazu Adachi; Yoshifumi Shibuya; Akihisa Murata; Yuho Tsuno

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
259 KB
Volume
25
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Substituent effects of p-Me0 and p-MeS groups deactivated by additional m-substituents in cumyl and a-phenylethyl solvolyses were studied to provide evidence for the higher resonance demand in the a-phenylethyl system.

๐Ÿ“œ SIMILAR VOLUMES

Substituent effect on the solvolysis of
Substituent effect on the solvolysis of ฮฑ-t-butyl-ฮฑ-methylbenzyl chlorides
โœ Mizue Fujio; Hideyuki Nomura; Kazuhide Nakata; Yoshihiro Saeki; Masaaki Mishima; ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 454 KB

The substituent elp"ct on the solvoiysis r&es of a-t-but+a-methylbmzyi chlorides in 80% aq. wetone ws correlated to give p=43 and r=0.91 in knrrs of the LArSR Eq-(I}. T&s slight@ reduced r value

Pressure Effects in the Solvolysis of Be
Pressure Effects in the Solvolysis of Benzyl Chlorides
โœ K. J. Laidler; R. Martin ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 615 KB

Rates of solvolysis of benzyl chloride and of substituted benzyl chlorides have been measured in an acetone-water mixture (acetone mole fraction 0.147) at pressures ranging from atmospheric to 1 kbar. Pressure studies have also been made for p-methyl benzyl chloride in various acetone-water mixtures