## Abstract When the __Hammett‐Taft__ equation log (__k/k__~o~)=ρ^q^ · σ is applied to the solvolysis of the 3‐substituted propyl bromides **6a‐6i** in ethanol/water 4:1 __(v/v)__ log __k__ correlates linearly with σ except in cases where R exerts an anchimeric effect. The reaction constant ρ^q^ fo
Polar Substituent Effects in the Solvolysis of Acyclic Tertiary Chlorides Polar Effects VI
✍ Scribed by Cyril A. Grob; Adrian Waldner
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- German
- Weight
- 415 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0018-019X
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📜 SIMILAR VOLUMES
## Abstract The rate constants for 3‐substituted adamantyl __p__‐toluenesulfonates **3a**‐**3k** in ethanol/water 80:20 correlate well with the respective inductive substituent constants σ. The reaction constant ρ for the toluenesulfonates **3** is 10% larger than for the corresponding bromides **2
Hydrolysisofbicyclo[2.2.2]octylp-nitrobenzenesulfonate (14a,X =p-N02C6H4S03), and nineteen 4-R-substituted derivatives 14b-14 t in 70% aqueous dioxane yield the corresponding bicyclo [2.2.2]octanols 14 (X = OH), exclusively. The 7-center fragmentation to 1,4-dimethylidene-cyclohexane (15) is not obs
According to the equation log k = pl.rri' + log k,.
The rates of solvolysis in various solvents at 25 °C were determined for five tertiary alkyl chlorides: 2-chloro-2,4,4-trimethylpentane ( 4), 2-chloro-2,4-dimethylpentane, 2-chloro-2-methylpentane, 1-chloro-1,3,3-trimethylcyclopentane (7) and 1-chloro-1-methylcyclopentane. The rate data were analyse