Polar Effects. Part 15. Twin γ-substituent effects in the formation of adamantyl-1-cations

Polar Effects. X. Polar Substituent Effe

Polar Effects. X. Polar Substituent Effects in the Solvolysis of 3-Substituted 1-Adamantyl Bromides and Toluenesulfonates

✍ Cyril A. Grob; Bruno Schaub 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 German ⚖ 413 KB 👁 1 views

## Abstract The rate constants for 3‐substituted adamantyl __p__‐toluenesulfonates **3a**‐**3k** in ethanol/water 80:20 correlate well with the respective inductive substituent constants σ. The reaction constant ρ for the toluenesulfonates **3** is 10% larger than for the corresponding bromides **2

Polar Effects. Part 15. Twin γ-substituent effects in the formation of adamantyl-1-cations

✦ Synopsis