Resolution of racemates by ligand-exchange chromatography on sorbents based on L-serine, L-threonine, and L-tyrosine
β Scribed by I. I. Peslyakas; S. V. Rogozhin; V. A. Davankov
- Book ID
- 112438287
- Publisher
- Springer
- Year
- 1974
- Tongue
- English
- Weight
- 169 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1573-9171
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A series of monomers based on the methyl, ethyl, and isopropyl esters of N a -(methacryloyl)-serine and -threonine were synthesized, and used in an AIBN-initiated radical polymerization reaction to yield polymers with an M n ranging between 6.6 and 23.8 kDa. The newly synthesized polymers showed LCS
## Abstract Ligandβexchange chromatography is shown to be applicable for obtaining the optical isomers of [^3^H]valine. Data are presented showing the effect of the asymmetric sorbent's structure on its kinetic properties and the optimum conditions selected for the chromatographic resolution of D,