The removal of mercury from smooth mercury poisoned platinum electrodes by means of simultaneous hydrogen evolution is described. It is caused by volatility of mercury and its evaporation into the stream of electrolytically discharged hydrogen. The kinetic equation for this process is derived and li
✦ LIBER ✦
Research Topic — Catalysis of Hydrogen Evolution on Mercury Electrodes
✍ Scribed by Michael Heyrovsky
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 8 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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In unbuffered aqueous solution, the hydrogen evolution at iron electrodes is usually first order in hydrogen-ion dependence at pH below about 7 and pH independent at higher pHC1-41. This indicates that hydrogen ions and water molecules are the main electroactive reactants for this reaction in acid a