Influence of mercury on hydrogen overvoltage on solid metal electrodes—II. Desorption of mercury from electrodes caused by cathodic evolution of hydrogen
✍ Scribed by J. Vondrák; J. Balej
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 830 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
✦ Synopsis
The removal of mercury from smooth mercury poisoned platinum electrodes by means of simultaneous hydrogen evolution is described. It is caused by volatility of mercury and its evaporation into the stream of electrolytically discharged hydrogen. The kinetic equation for this process is derived and limitations of its validity are established and discussed. At higher values of current density and temperature, a platinum electrode is not poisoned in a medium containing traces of mercury ions. The behaviour of nickel and cbbalt electrodes is similar. R6smnMn a trouv6 que l'empoisonnement par le mercure des 6lectrodes de Pt, Ni et Co pour l'&olution d'hydrog&ne est seulement transitoire et qu'il est caus6 par la volatilite du mercure et par le transport de ses vapeurs dans l'hydrogbne gazeux, dont 1'6volution pro&de & l%lectrode en meme temps. On a d6duit lea reIations cinbtiques pour la desorption de mercure des 6lectrodes de Pt comme fonction du courant d'8volution d'hydrogkne, de la pression et de la temp&ature; leurs limitations ont 6t6 determinbs et discut&s. En cas de courant et de temperature suffisamment 6lev6s et de petite concentration du mercure en solution, les dlectrodes ne sont pas empoisonn&es enti&rement.
📜 SIMILAR VOLUMES
Mercury deposited in amounts of the order of a few monolayers on Pt, Fe, Ni and Co raises the overvoltage of hydrogen evolution in alkaline solution. On Cr it deaeases and on MO it has little influence, but these metals corrode in alkali. the overvoltage R&mn&Le mercure deposal en quantit&s de l'ord