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Reprint of: Quantum yield of chlorine-atom formation in the photodissociation of chlorine peroxide (ClOOCl) at 308nm

✍ Scribed by Molina, M.J.; Colussi, A.J.; Molina, L.T.; Schindler, R.N.; Tso, T.-L.

Book ID: 123236583
Publisher: Elsevier Science
Year: 2013
Tongue: English
Weight: 333 KB
Volume: 589
Category: Article
ISSN: 0009-2614
DOI: 10.1016/j.cplett.2013.08.067

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The production of Cl atoms in the laser flash photolysis of ClOOCl at 308 nm has been investigated by time-resolved atomic resonance fluorescence at 235 K. A value of @= 1.03 f 0. I2 has been obtained for the primary quantum yield based on an absorption cross section ratio u&u~~s=22 for CIOOCI at 24

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