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Reported Asymmetric Synthesis of Santonin

โœ Scribed by CIBSON, CHARLES S.


Book ID
109543173
Publisher
Nature Publishing Group
Year
1944
Tongue
English
Weight
133 KB
Volume
153
Category
Article
ISSN
0028-0836

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AbstractรThis article reports on the transformation of santonin into two C 10 -epimeric 3-oxa-guaianolides which are 8-deoxyderivatives of several natural 3-oxaguaianolides isolated from Achillea species. The synthesis involved the photochemical rearrangement of the eudesmane skeleton into a guaiane