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Rendering Schrock-type Molybdenum Alkylidene Complexes Air Stable: User-Friendly Precatalysts for Alkene Metathesis

✍ Scribed by Dipl.-Chem. Johannes Heppekausen; Prof. Alois Fürstner

Book ID: 101547551
Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 342 KB
Volume: 123
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.201102012

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## Abstract The decomplexation of phenanthroline or bipyridine ligands from several molybdenum alkylidene complexes using ZnCl~2~ as activation agent releases tetracoordinate molybdenum complexes, which catalyze high‐yielding metathesis reactions under mild conditions (the activation is carried out