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Remote, anodic rearrangement-substitution reaction of aliphatic ketones

✍ Scribed by Becker, James Y.; Byrd, Larry R.; Miller, Larry L.


Book ID
127169446
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
254 KB
Volume
96
Category
Article
ISSN
0002-7863

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Ahatract -The anodic oxidation of aliphatic ketones at a smooth Pt electrode in TFA/Bu,NBF, has been studied. It is shown that, in general, the reaction leads to the formation of a trifluoroacetate ester at a carbon atom remote from the k&o-group; on work up the products were either hydroxy ketones,