Remote, anodic rearrangement-substitution reaction of aliphatic ketones
β Scribed by Becker, James Y.; Byrd, Larry R.; Miller, Larry L.
- Book ID
- 127169446
- Publisher
- American Chemical Society
- Year
- 1974
- Tongue
- English
- Weight
- 254 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The fragmentation reactions of glycidic methyl ester (1) and of its derivatives (26) substituted by one, two and three methyl groups, respectively, at the oxirane ring, of the corresponding glycidols (7-12), and of the glycidyl ethers (13-16) in the 70 eV mass spectra have been studied using isotopi
Ahatract -The anodic oxidation of aliphatic ketones at a smooth Pt electrode in TFA/Bu,NBF, has been studied. It is shown that, in general, the reaction leads to the formation of a trifluoroacetate ester at a carbon atom remote from the k&o-group; on work up the products were either hydroxy ketones,