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Remote 1,5-stereoinduction in boron aldol reactions of methyl ketones: application to the convergent assembly of the 1,3-polyol sequence of (+)-roxaticin

โœ Scribed by Ian Paterson; Lynne A. Collett


Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
155 KB
Volume
42
Category
Article
ISSN
0040-4039

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โœ I. PATERSON; K. R. GIBSON; R. M. OBALLA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 34 KB ๐Ÿ‘ 2 views

Remote, 1,5-anti Stereoinduction in the Boron-Mediated Aldol Reactions of ฮฒ-Oxygenated Methyl Ketones. -The title reaction is investigated with different kinds of aldehydes leading to the desired aldol products with a high level of substrate-based 1,5-stereocontrol. The products are suitable syntho