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Remarkable Steric Effects and Influence of Monodentate Axial Ligands L on the Spin-Crossover Properties of trans-[FeII(N4 ligand)L] Complexes

✍ Scribed by Costa, José Sánchez; Lappalainen, Kristian; de Ruiter, Graham; Quesada, Manuel; Tang, Jinkui; Mutikainen, Ilpo; Turpeinen, Urho; Grunert, C. Matthias; Gütlich, Philipp; Lazar, Hanane Zhor

Book ID: 115541425
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 354 KB
Volume: 46
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic0624017

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## Abstract A series of new rhenium(I) complexes of the type [Re^I^(CO)~3~(L)(L′)]^__n__+^ (L = 2,2′‐biquinoline (bqui) or 3,3′‐(ethane‐1,2‐diyl)‐2,2′‐biquinoline (CH~2~CN~2~)bqui); L′ = CF~3~SO$\rm{\_3^ - }$, pyridine (py), or 4‐substituted pyridine (HOpy, Bzpy, or NCpy); __n__ = 0 or 1) were prep