✦ LIBER ✦

The influence of the steric properties of the ligands PR2Ph and L on the formation and properties of the complexes Mo(η6-PhPR2)(L)(PPh2CH2CH2PPh2), R = Et, L = PPhEt2 and R = Ph, L = PPh3, PR′3, CO, CNR, N2, H2

✍ Scribed by James J. Frizzell; Rudy L. Luck; Robert H. Morris; Shane H. Peng

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 850 KB
Volume: 284
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(85)87215-6

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Carbene complexes: XXII. Preparation, pr

Carbene complexes: XXII. Preparation, properties and structures of the N,N-functionalized bis(amino)carbenemolybdenum(O) carbonyls [Mo(CO)4 {CN(CH2CH:CH2)(CH2) 2N}(CH2CH:CH2)}] and Mo(CO)3{CN[(CH2)3PPh2] (CH2)2N {(CH2)3PPh2}]n

✍ José A. Chamizo; Peter B. Hitchcock; Hatam A. Jasim; Michael F. Lappert 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 780 KB

The formation of alkyne and alkynyl comp

The formation of alkyne and alkynyl complexes by reaction of 1-alkynes with trans-[M(N2)2(PH2PCH2CH2PPh2)2] (M  Mo OR W) and with [Mo(Ph2PCH2PPh2)3]: X-ray structure of trans-[Mo(CCPh)2(PH2PCH2CH2PPh2)2]

✍ Nor.A. Buang; David L. Hubhes; Neimat Kashef; Raymond L. Richards; Armando J.L. 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 299 KB

Reversible CH Bond Activation Reactions

Reversible CH Bond Activation Reactions of the N-Heterocyclic Carbene Ligands in Ru(Ph2PCH2CH2CH2PPh2)(IMes)(CO)H2 and Ru(Ph2AsCH2CH2PPh2)(IMes)(CO)H2 (IMes=1,3-Dimesityl-1,3-dihydro-2H-imidazol-2-ylidene)

✍ Mark J. Chilvers; Rodolphe F. R. Jazzar; Mary F. Mahon; Michael K. Whittlesey 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 118 KB 👁 2 views

## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3‐dimesityl‐1,3‐dihydro‐2__H__‐imidazol‐2‐ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~–H CH bond activation of the __N__‐heterocy

Preparation and spectroscopic properties

Preparation and spectroscopic properties of a series of new bimetallic phosphine-bridged seven-coordinate complexes of the type [M4I4(CO)6L2(μ-L L] {M = Mo or W; L = PPh3, AsPh3 or SbPh3; L L = Ph2P(CH2)nPPh2 (n = 1, 2 or 4); L L = [Fe(η5-C5H4PPh2)2]}

✍ Paul K. Baker; Marit van Kampen; Dafydd ap Kendrick 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 361 KB

Reactivity of [N(CH2CH2PPh2)3]Ni toward

Reactivity of [N(CH2CH2PPh2)3]Ni toward CS2, SCNPh, and COS. Structure of the η2S,C-bonded phosphoniodithiomethyl ester complex [Ph2PCH2CH2N(CH2CH2PPh2)2Ni(CS2Me)]BPh4

✍ Claudio Bianchini; Carlo A. Ghilardi; Andrea Meli; Annabella Orlandini 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 853 KB

Carbene complexes: XXIII. Preparation, c

Carbene complexes: XXIII. Preparation, characterisation, and structures of the enetetramine-derived carbenerhodium(I) chloride complexes [RhCl(LR)3],trans-[RhCl(CO)(L2R′)], and [{RhCl(COD)}2{μ-L2(323)R}] [L2R or R′ = CN(R or R′)(CH2)2NR(or R′) (R  CH2)Ph or Et, R′  Me) and L(323)R  CN(R)(CH2)3N(CH2)2N(CH2)3N(R)C (R  CH2Ph)]

✍ Bekir Çetinkaya; Peter B. Hitchcock; Michael F. Lappert; David B. Shaw; Kostas S 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 588 KB