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Remarkable stabilizing effects of silyl group on furfuryl chlorides and furfuryl Grignard reagents

✍ Scribed by Keijiro Takanishi; Hirokazu Urabe; Isao Kuwajima

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 125 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96101-x

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✦ Synopsis

Sumnary: By introducing a silyl group on their 5-position, furfuryl chlorides and the Grignard reagents have been stabilized remarkably and the Grignard reagents have exhibited unusual ambident behavior toward several electrophiles. Different from other organic halides, furfuryl chlorides are usually quite unstable and difficult to manipulate for synthetic purposes.1 Extreme lability of

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