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Remarkable regio-controlled effect of 1,3-diene as a ligand on nickel-promoted cyclization

โœ Scribed by Yoshihiro Sato; Masanori Takimoto; Miwako Mori


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
214 KB
Volume
37
Category
Article
ISSN
0040-4039

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A pseudodisaccharide, a 5-0-Q?-D-mannopyranosyl)-2-deoxystreptamine derivative, was obtained preferentially when 2,3&tri-O-ally&6-0-benzyl-a-D-mannopyranosyl chloride (1) was used as the glycosyl donor for coupling with I ,3-di-~-~nzyloxyc~bonyl-Z-d~xyst~ptamine (2) usmg silver t&late as a promoter