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Remarkable In/out Inversions at Bridgehead Phosphorus Atoms

✍ Scribed by Roger W. Alder; David Read

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
127 KB
Volume
112
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

Staudinger Reaction at in-Bridgehead Pos
Staudinger Reaction at in-Bridgehead Positions of Phosphorus Macrobicyclic Compounds
✍ Ingmar Bauer; Margit Gruner; Sigrid Goutal; Wolf D. Habicher 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB

## Abstract Reaction of __in__,__in__‐phosphite **1** with thiophosphoryl azide **2** affords __in__,__in__‐dithiophosphate **3**, __in__,__in__‐thiophosphate–imidophosphate **4**, and __in__,__in__‐phosphite–imidophosphate **5**. Compounds **4** and **5** are the first examples of the modification