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In,out-Isomerism of Phosphorus Bridgehead Cage Compounds

✍ Scribed by Ingmar Bauer; Wolf D. Habicher

Publisher
John Wiley and Sons
Year
2004
Weight
10 KB
Volume
35
Category
Article
ISSN
0931-7597

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Staudinger Reaction at in-Bridgehead Pos
Staudinger Reaction at in-Bridgehead Positions of Phosphorus Macrobicyclic Compounds
✍ Ingmar Bauer; Margit Gruner; Sigrid Goutal; Wolf D. Habicher 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB

## Abstract Reaction of __in__,__in__‐phosphite **1** with thiophosphoryl azide **2** affords __in__,__in__‐dithiophosphate **3**, __in__,__in__‐thiophosphate–imidophosphate **4**, and __in__,__in__‐phosphite–imidophosphate **5**. Compounds **4** and **5** are the first examples of the modification