RELATIVE RATES OF REACTION OF OZONE WITH OLEFINS IN THE VAPOR PHASE
✍ Scribed by Vrbaski, T.; Cvetanović, R. J.
- Book ID
- 111682465
- Publisher
- NRC Research Press
- Year
- 1960
- Tongue
- French
- Weight
- 284 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0008-4042
- DOI
- 10.1139/v60-146
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Reactions of ozone with simple olefins have been studied between 6 and 800 mtorr total pressure in a 220-m3 reactor. Rate constants for the removal of ozone by an excess of olefin in the presence of 150 mtorr oxygen were determined over the iemperature range 280 to 360" K by continuous optical absor
With a view to investigating the relative rates of combustion of the olefins, known mixtures of ethylene and propene and of ethylene and isobutene were exploded with oxygen, and the proportion of each olefin remaining unburned was found by analysis of the products. One slow combustion was also made
## Abstract A mechanism for ozone–olefin reactions is developed that is consistent with the recent findings of several investigations. These findings suggest a reaction sequence leading to the production of fewer free radical species than has been assumed in the past. Computer simulations using the