Relative Rates of Grignard Addition and Reduction Reactions 1-3
โ Scribed by Miller, John; Gregoriou, George; Mosher, Harry S.
- Book ID
- 127005486
- Publisher
- American Chemical Society
- Year
- 1961
- Tongue
- English
- Weight
- 744 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Th8 competitive addition-reduction of 2,kdlmethyl-3-pento rith %.PrHgRra vas studied using the procedure described earlier'. The reaction vas followed by quantitative vapour pba8e chromatogra phY2 analysis of the products. The Grlgnard reagent was prepared by reaction of n.propylbromlde vlth magne-
The title reaction afforded selenophilic, carbophilic, and reduction products depending on the kinds of the organometallic reagents and the heterophilic nature of the reaction was more conspicuous in the reaction with the selenoketone than with the corresponding thioketone.