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Relative Rates of Chromic Acid Oxidation of Naphthalenes and Fluorenes in Acetic Acid

✍ Scribed by Ogata, Yoshiro; Akimoto, Hiroyuki


Book ID
127095769
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
322 KB
Volume
27
Category
Article
ISSN
0022-3263

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## Abstract The linear free energy relationship of __Sicher__ for relative reactivity towards chromic acid oxidation (ΔΔ__G__) as a function of thermodynamic stability (Ξ”__G__) has been reexamined with 23 pairs of epimeric alcohols. The plot of Ξ”__G__ __vs__. Ξ”__G__ has a slope of 0.8, a correlatio