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Relative Rates of Base-Catalyzed Racemization and Deuterium Exchange of Aryl 2-Octyl Sulfones 1

โœ Scribed by GOERING, HARLAN L.; TOWNS, DONALD L.; DITTMAR, BRUCE


Book ID
120479208
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
489 KB
Volume
27
Category
Article
ISSN
0022-3263

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## Abstract A synthesis and a baseโ€catalyzed exchange reaction was developed under mild conditions to deuterate and subsequently tritiate the methyl group of the base sensitive diketone 1โ€biphenylโ€4โ€ylpropaneโ€l,2โ€dione depicted in Figure 1. Using Et~3~N as base, deuterium incorporation of the methy