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Relative Rate and Product Studies of the OH−Acetone Reaction

✍ Scribed by Raff, Jonathan D.; Stevens, Philip S.; Hites, Ronald A.

Book ID
127360877
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
156 KB
Volume
109
Category
Article
ISSN
1089-5639

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The gas phase reaction of OH radicals with dimethyl sulfide (CH,SCH,, DMS) has been studied using both an absolute and a relative technique a t 295 2 2 K and a total pressure of 1 atm. The absolute rate technique of pulse radiolysis combined with kinetic spectroscopy was applied. Using this techniqu