Mixed metal phosphates of the general formula \(A_{x} \mathrm{TiV}^{\mathrm{II}}\left(\mathrm{PO}_{4}\right)_{3}\), where \(A=\mathrm{Na}\), \(\mathrm{K}\), or \(\mathrm{Ba}\) and \((0<x \leq 3)\), have been synthesized. While the sodium phosphate, \(\mathrm{Na}_{3} \mathrm{TiV}\left(\mathrm{PO}_{4}
Relationships between structure and magnetic properties of titanium(III) nasicon-type phosphates
β Scribed by A. El Jazouli; A. Nadiri; J.M. Dance; C. Delmas; G. Le Flem
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 425 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-3697
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π SIMILAR VOLUMES
The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co 0.5 Ti 2 (PO 4 ) 3 were simultaneously reproduced by use of a crystal field theory involving a set of F k , , free ion, and B k q crystal fi
The phosphate Cu I 0.5 Mn II 0.25 Zr 2 (PO 4 ) 3 can be obtained at 10003C by exchange reaction in Cu II 0.5 Zr 2 (PO 4 ) 3 . It crystallizes in the rhombohedral system (space group R3 ) with the parameters a h β«Ψβ¬ 8.8352(1) A s and c h β«Ψβ¬ 22.254(5) A s in the equivalent hexagonal cell. The structu