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Relationship between the Conrad-Wiedersich and the Schoeck expression for activation energy

✍ Scribed by A. Pawełek

Publisher
Elsevier Science
Year
1985
Weight
218 KB
Volume
72
Category
Article
ISSN
0025-5416

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✍ Roland H. Smith 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 422 KB

The rate constant k4 has been measured a t 268", 298", and 334°K for the reaction CH20 + 2 0 H -CO + 2H20 relative to that for OH + OH ( k 2 ) by competition experiments in a discharge flow tube using mass-spectrometric analysis. Based on k2 = 2.24 X lO-l2cm3/ moleesec a t 298°K and E P = 4 kJ/mol,