✦ LIBER ✦

Rate constant and activation energy for the gaseous reaction between hydroxyl and formaldehyde

✍ Scribed by Roland H. Smith

Publisher: John Wiley and Sons
Year: 1978
Tongue: English
Weight: 422 KB
Volume: 10
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550100509

No coin nor oath required. For personal study only.

✦ Synopsis

The rate constant k4 has been measured a t 268", 298", and 334°K for the reaction CH20 + 2 0 H -CO + 2H20 relative to that for OH + OH ( k 2 ) by competition experiments in a discharge flow tube using mass-spectrometric analysis. Based on k2 = 2.24 X lO-l2cm3/ moleesec a t 298°K and E P = 4 kJ/mol, k 4 = (6.5 f 1.5) X 10-12cm3/molec.sec at 298°K and E4 = (6 f 2)kJ/mol.

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