The variations of the dynamic mechanical properties (at 5 Hz) of bitumen-SBS mixes in the function of their composition (polymer content, bitumen composition) have been established. The relationships between the viscoelastic measurements and the morphological characteristics, previously determined,
Relationship between polymerization conditions and rheological properties for styrene-acrylonitrile copolymers
✍ Scribed by A. García-rejón; C. Rangel-nafaile; L. Ríos; F. Cid
- Publisher
- Society for Plastic Engineers
- Year
- 1983
- Tongue
- English
- Weight
- 541 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0032-3888
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✦ Synopsis
Abstract
Styrene‐acrylonitrile (SAN) copolymers are widely used in industrial applications in the fields of appliances, automotive, housewares, medicine, and packaging. They possess most of the features of polystyrene, with improved resistance to chemical attack, stress eracking, and heat deflection, and with greater strength and toughness. Their properties depend on several factors, the most important being the composition of the feed (monomer ratio), the type and quantity of the initiator, and the solvent to monomer ratio in the feed. This work presents the results of a continuing program that studies the effect of the above‐mentioned polymerization variables on the viscoleastic properties, and the way in which these variables can be adjusted in order to obtain a SAN copolymer with specific properties.
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The variation, with temperature, of the dynamic mechanical properties (at 5 Hz) of bitumen-SBS mixes has been established. Typical features of the storage modulus, the loss modulus, and the loss angle variations with temperature could be attributed to the different phases that compose the mix. Final
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