Relationship between four-state delineation and two-state delineation in electron transfer reactions and excitation transfer
β Scribed by Toshiaki Kakitani
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 563 KB
- Volume
- 225
- Category
- Article
- ISSN
- 0020-1693
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π SIMILAR VOLUMES
The vibrational energy relaxation (VER) of polyatomic molecules has been the central issue in many of the chemical reactions in condensed phase [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17] as well as in gas phase . The vibrational energy introduced to the molecule is immediately redis
It is shown that miscd electron transfer tluorescencc quenching espcriments in which formation of the fluorcscer triplet state is effectively inhibited ullow new electron transfer reactions to bc invcstigatcd. The rate constants obtaincd are discussed with rcspcct to the free-energy changes involved
## Abstract The rate constants for the reaction of electron pulse produced solvated electrons and a number of solutes in waterβisopropanol mixtures have been measured. The quenching of the singlet excited state of naphthalene has also been studied in the same mixtures, using triethylamine and acryl