Relations linéaires enthalpies-entropies complexation de l'argent par des pyridines substituées
✍ Scribed by G. Berthon; O. Enea; Y. Fuseau
- Book ID
- 103409063
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 1022 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-6031
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The present work concerns the photodegradation of macromolecules having phenyl and carbonyl groups along the main chain. The photochemical behaviour of different polyketones is expected to give useful information about the mechanisms of the reaction. With this purpose we have considered polyketones
Complexation constants of hydrogen bonded complexes between substituted phenols and substituted pyridines were determined by infrared spectroscopic measurements in carbon tetrachloride at 25OC. It was previously shown that for monosubstitutedJcomplexes the complexation constant Kab obied the relatio