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Reinvestigation of the electron affinities of O2 and NO

✍ Scribed by Michael J. Travers; Daniel C. Cowles; G.Barney Ellison


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
422 KB
Volume
164
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES


An ab initio study of the electron affin
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Coupled pair functional, multiconfigurational second-order perturbation theory, and multireference CI methods have been applied in a calculation of the electron affinity of the oxygen molecule. The convergence of the theoretical result has been checked with respect to a systematic expansion of the o

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The electron affinities of the Ianthanides (La through Lu) are estimated by considering the energy variations associated with changes in the 4f orbital population. The ground-state electron affmities are all predicted to be within therange +O.S eV to -0.3 eV.

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The binding energies of water and methanol to NO: have been measured 10 be 14.8 k 2.3 and 19.2 ? 2.3 kcal/mol, respectively, using energy-resolved collision-induced dissociation of H#-NO: and CH,O( H )-NO: in a flowing afterglow triple quadrupole apparatus. These values are used with literature ther